Síntese e propriedade fotoluminescente do core-shell Ca(1-x)TiO3:Yb(x)@Ca(1-y)TiO3:Er(y)

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Universidade Federal de Goiás


In recent years, research in the nanocomposites area of core-shell type increased significantly. The core-shell type nanoparticles with photoluminescence properties (PL) attract much attention from the scientific community. Are also of great interest nanoparticles that exhibit the upconversion energy, i.e. they absorbing low energy photons and emission high-energy photons. The present work has as objective nanocomposites synthesis of core-shell type, with CaTiO3 matrix (CT) and doped with rare earth ions Er3+ and Yb3+ in a variety composition and variations, to analysis the photoluminescent properties. The nanoparticles of the core and shell were obtained by the Method of Polymeric Precursors. The samples were characterized by X-ray diffraction (XRD) for structural characterization, and it was found that All samples presented the perovskite structure of the orthorhombic type. The characterization by Transmission Electron Microscopy (TEM) failed to demonstrate the formation of core-shell, requiring analysis by Energy Dispersive X-ray (EDX), which showed the presence of rare earth Er3+ and Yb3+ in the different layers. The UV-Vis gap allowed the calculation of the shell and core samples. The PL emission results were used to relate the thickness of the shell and the intensity of the emission. On the other hand, to study the upconversion energy, core materials showed a higher intensity than in the core-shell; the best intensity in the core-shell was found with doping the core with Yb3+ and Yb3+ with shell and Er3+ suggesting the transfer of energy between the layers.



Core-shell, Método dos precursores poliméricos, Conversão ascendente de energia, Perovsquita, Core-shell, Method of polymeric precursors, Upconversion, Perovskite


EDUARDO, A. C. Síntese e propriedade fotoluminescente do core-shell Ca(1-x)TiO3:Yb(x)@Ca(1-y)TiO3:Er(y). 2015. 59 f. Dissertação (Mestrado em Química) - Universidade Federal de Goiás, Catalão, 2015.