Síntese do Fe3O4@SiO2:phen:Eu3+: um nanocompósito magnético luminescente visando aplicações biomédicas

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Universidade Federal de Goiás


Among the various iron oxides studied, a magnetite (Fe3O4) stands out due to its superparamagnetic behavior and its high biocompatibility. Luminescent properties working cooperatively in magnetic nanoparticles with which the material converts certain types of energy into emission of electromagnetic radiation at the same time, which enables an interaction by magnetic fields. In the present work, an investigation and structural, elemental and morphological analysis of superparamagnetic / luminescent particles formed by coating of iron oxide by an SiO2 base network was carried out. The Fe3O4 oxide was synthesized by the coprecipitation method, and in the Eu3+ rare earth together with the 1,10-phenanthroline linker in the network, were responsible for energy transfer processes in systems that checked as optical materials for materials. The nanocomposites synthesized obeyed the formation of a core-shell system and was verified by micrographs obtained by Electron Transmission Electron Microscopy, evidencing a formation of nanoparticles of varied sizes. As the compositions of the phases of the materials were characterized by X-ray Diffraction, Radiated Spark Energy and Absorption Spectroscopy in the Infrared region, showing a crystal phase of the magnetic oxide and a formation of nanocomposite. The properties of interest (magnetism and photoluminescence) were evaluated and the respective results presented agreed with each other, with characteristic emissions of Eu3+ emitting a pink coloration, and an emission intensity for a concentration of this species in the material. The materials presented a superparamagnetic behavior, evidencing that the oxide coating did not change as Fe3O4 magnetic characteristics, and is in turn presented in a saturation magnetization of 55 emu / g with a magnetic domain of 8.9 nm. As nanoparticles have dimensions that indicate that a part has a magnetic domain.



Magnetismo, Nanocompósito, Fotoluminescência, Core-shell, Magnetism, Nanocomposite, Photoluminescence, Core-shell


SILVA, R. L. S. Síntese do Fe3O4@SiO2:phen:Eu3+: um nanocompósito magnético luminescente visando aplicações biomédicas. 2017. 74 f. Dissertação (Mestrado em Química) - Universidade Federal de Goiás, Catalão, 2017.